abbr. SJ GMU
ISSN 2657-5841 (printed)
ISSN 2657-6988 (online)
DOI: 10.26408
Wpływ termicznego efektu Marangoniego na kinetykę rozpościerania substancji ropopochodnych na morzu
Thermal Marangoni Effect on Crude Oil Substance Spreading Kinetics on the Sea
https://orcid.org/0000-0003-1693-6623Abstract:
Dynamics of liquid hydrocarbons spreading over the seawater surface was studied in laboratory conditions. Oil lens expansion rates predicted from classical theories were higher 6–9 times than these measured experimentally. Such a discrepancy could result from onset of Benard-Marangoni cellular flow beneath the expanding oil, observed for volatile hydrocarbons. The vertical temperature gradient ?Tcool related to the evaporation rate was high enough to initiate Marangoni thermal phenomenon. The additional dissipative, turbulent flow is likely to slow down the spreading. The classical Marangoni effect is of secondary importance in reference to the thermal effect in interfacial spreading and mixing processes at sea.
Streszczenie:
Dynamikę rozpościerania ciekłych węglowodorów na powierzchni oryginalnej wody morskiej, badano w warunkach laboratoryjnych. Szybkość ekspansji soczewek olejowych, przewidywana przez klasyczną teorię, okazała się większa o czynnik 6–9 od wartości mierzonej eksperymentalnie. W artykule postuluje się, że ta niezgodność wynika z aktywacji tzw. cyrkulacji Benarda-Marangoniego, szczególnego ruchu płynu, bezpośrednio pod powierzchnią ekspandującej cienkiej warstwy węglowodoru, obserwowanego dla lotnych cieczy. Pionowy gradient temperatury ?Tcool, proporcjonalny do szybkości parowania, wywołany efektem schłodzenia powierzchni w procesie parowania, okazał się dostatecznie duży, aby przekroczyć wartość progową dla wszystkich badanych cieczy i wywołał efekt Marangoniego. Dodatkowy turbulentny przepływ płynu, towarzyszący rozpościeraniu oleju, prawdopodobnie powoduje spowolnienie szybkości ekspansji. Klasyczny efekt Marangoniego (powodowany naturalnymi surfaktantami) ma nieznaczny udział w procesach mieszania i rozpościerania w morzu.
Słowa kluczowe:
pochodne ropy naftowej
kinetyka rozpościerania
gradienty temperatury
cyrkulacja Benarda-Marangoniego
Issue:
Pages:
20
36
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